REACTIVITY OF DITHIOPHOSPHORIC ACID TOWARDS SULFURATED MONOSUBSTITUTED ALKYNES IN PRESENCE OF TRANSITION-METAL-CATALYST

Authors
DODINCARNOT V STEPHAN B CURCI M MIELOSZYNSKI JL PAQUER D
Citation
V. Dodincarnot et al., REACTIVITY OF DITHIOPHOSPHORIC ACID TOWARDS SULFURATED MONOSUBSTITUTED ALKYNES IN PRESENCE OF TRANSITION-METAL-CATALYST, Phosphorus, sulfur and silicon and the related elements, 117, 1996, pp. 225-230
Citations number
2
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
117
Year of publication
1996
Pages
225 - 230
Database
ISI
SICI code
1042-6507(1996)117:<225:RODATS>2.0.ZU;2-K
Abstract
The reactivity of sulfurated monosubstituted alkynes with dithiophosph oric acid (noted Z-H) has been investigated. Depending on the transiti on-metal-catalyst (Ni, Pd, Rh) and solvent (benzene or THF), two types of alkenes can be isolated: Z-CH=CH-CH2-SR and/or Z-C(CH2-SR)=CH2. Th e selectivity of this reaction was studied. C-13 and P-31 NMR of these new sulfurated alkenes are reported.