A new anhydrous hydrogen fluoride (AHF) vapor-phase etch process, at t
he heart of a commercial single-wafer system, dramatically reduces the
number of process steps for fabrication of complex three-dimensional
device structures, including cylindrical capacitors for 256-Mbit and 1
-Gbit DRAMs. Controlling process temperature, HF concentration, and va
por flow, the process enhances natural etch-selectivity differences of
doped and undoped oxides. These natural differences stem from adsorbe
d water content in oxides. The process is capable of routine doped-to-
undoped oxide etch selectivities > 1000:1.