An experimental study on explosive interaction between transparent mel
t (T = 1120 K) and entrapped water (T = 300 K) has been performed. Int
ense explosions occurred, resulting from catastrophic fragmentation of
the melt and increasing heat transfer to the water in a cascading pro
cess. In earlier experiments a quasi-isochoric brittle reaction of the
melt was identified to be the major explosion mechanism. Using a tran
sparent melt, this brittle reaction could directly be observed by high
-speed cinematography. The pictures revealed two fragmentation mechani
sms: a) formation of leading cracks (mm to cm scale) due to excess wat
er pressure, and b) slower mu m scaled melt fragmentation induced by s
train build-up in the melt during rapid cooling.