DIIODOTETRAKIS[TRIS(DIMETHYLAMINO)-PHOSPHINE OXIDE-O]BISMUTH(III) PENTAIODIDE, [BII2(OP(NME2)(3))(4)][I-5]

Authors
FARRUGIA LJ NORMAN NC PICKETT NL
Citation
Lj. Farrugia et al., DIIODOTETRAKIS[TRIS(DIMETHYLAMINO)-PHOSPHINE OXIDE-O]BISMUTH(III) PENTAIODIDE, [BII2(OP(NME2)(3))(4)][I-5], Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 476-479
Citations number
15
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
4
Pages
476 - 479
Database
ISI
SICI code
0108-2701(1998)54:<476:DOP>2.0.ZU;2-O
Abstract
The title compound, [BiI2(C6H18N3OP)(4)](I-5), contains the pseudo-oct ahedral Bi-III cation [BiI2{OP(NMe2)(3)}(4)](+), which has crystallogr aphic (4) over bar symmetry, and trans iodide ligands. The central I a tom of the disordered [I-5](-) anion is also situated on a site of (4) over bar symmetry and the atoms of this anion form an infinite three- dimensional network, resulting in a 'cage'-type structure. The cations are situated within the 'cage' cavities.