CYANOPHENYL)-2,2-DIMETHYL-1-PHENYLPROPANE-1-THIONE

Authors
FU TY SCHEFFER JR TROTTER J
Citation
Ty. Fu et al., CYANOPHENYL)-2,2-DIMETHYL-1-PHENYLPROPANE-1-THIONE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 496-497
Citations number
6
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
4
Pages
496 - 497
Database
ISI
SICI code
0108-2701(1998)54:<496:C>2.0.ZU;2-D
Abstract
The title molecule, C18H17NS, contains an all-trans arrangement of the central aliphatic system and exhibits an intramolecular S...beta H co ntact of 2.71 Angstrom, which is favourable for hydrogen abstraction i n a photochemical reaction. The angular parameters (describing the ori entation of the H atom relative to the thiocarbonyl plane) are close t o those expected for reaction via the (n,pi) excited state.