HYL-2-METHOXYMETHYLPYRROLIDINE-1-DITHIOCARBOXYLATE AND HYL-2-METHOXYMETHYLPYRROLIDINE-1-DITHIOCARBOXYLATE

Authors
BIEDERMANN M HARTUNG H DOLLING W VERJUS P
Citation
M. Biedermann et al., HYL-2-METHOXYMETHYLPYRROLIDINE-1-DITHIOCARBOXYLATE AND HYL-2-METHOXYMETHYLPYRROLIDINE-1-DITHIOCARBOXYLATE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 507-509
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
4
Pages
507 - 509
Database
ISI
SICI code
0108-2701(1998)54:<507:HAH>2.0.ZU;2-E
Abstract
The absolute configurations of both the enantiomers of the title compo und, C15H18BrNO2S2, have been determined. As expected, the molecular d imensions of both forms are insignificantly different. The phenacyl an d dithiocarbamate fragments are planar and approximately perpendicular to one another. The short N-C(=S) bond length [1.330 (7) Angstrom] in dicates involvement of the N-atom lone pair in the thiocarbonyl pi sys tem.