ROPHOSPHINOYL)-P-(DIISOPROPYLAMINO)MONOPHOSPHAZENE

Authors
HOKELEK T KILIC Z DAL H
Citation
T. Hokelek et al., ROPHOSPHINOYL)-P-(DIISOPROPYLAMINO)MONOPHOSPHAZENE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 523-525
Citations number
15
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
4
Pages
523 - 525
Database
ISI
SICI code
0108-2701(1998)54:<523:R>2.0.ZU;2-I
Abstract
The title compound, C6H14Cl4N2OP2, has an acyclic monophosphazene skel eton and a bulky diisopropylamino side group. The bulky substituent is instrumental in determining the molecular geometry. The P-N bonds hav e neither single-nor double-bond character and are substantially short er than the ideal P-N single bond. The P-N-P angle [134.0 (2)degrees] is similar to the angle found in cyclotetraphosphazenes, but wider tha n that in cyclotriphosphazenes.