POLY(ALPHA-TAU-BUTOXY-OMEGA-STYRYLO-GLYCIDOL) - A NEW REACTIVE SURFACTANT

Authors
DWORAK A PANCHEV I TRZEBICKA B WALACH W
Citation
A. Dworak et al., POLY(ALPHA-TAU-BUTOXY-OMEGA-STYRYLO-GLYCIDOL) - A NEW REACTIVE SURFACTANT, Polymer bulletin, 40(4-5), 1998, pp. 461-468
Citations number
16
Categorie Soggetti
Polymer Sciences
Journal title
Polymer bulletin → ACNP
ISSN journal
01700839
Volume
40
Issue
4-5
Year of publication
1998
Pages
461 - 468
Database
ISI
SICI code
0170-0839(1998)40:4-5<461:P-ANRS>2.0.ZU;2-B
Abstract
Poly(alpha-t-butoxy-omega-styrylo-ethoxy ethyl glycidyl ether) was syn thesized via the termination of the potassium t-butoxide initiated ani onic polymerization of ethoxy ethyl glycidyl ether with p-chloromethyl styrene. The macromonomer was copolymerized with styrene. Subsequent h ydrolysis of the copolymers leads to polystyrene - graft - polyglycido l. Poly(alpha-t-butoxy-omega-styrylo-glycidol), synthesized through th e hydrolysis of the macromonomer so obtained, acts as reactive emulsif ier (surfmer) in the emulsion copolymerization of styrene in water.