Atmospheric aerosols play important roles in climate and atmospheric c
hemistry: They scatter sunlight, provide condensation nuclei for cloud
droplets, and participate in heterogeneous chemical reactions. Two im
portant aerosol species, sulfate and organic particles, have large nat
ural biogenic sources that depend in a highly complex fashion on envir
onmental and ecological parameters and therefore are prone to influenc
e by global change. Reactions in and on sea-salt aerosol particles may
have a strong influence on oxidation processes in the marine boundary
layer through the production of halogen radicals, and reactions on mi
neral aerosols may significantly affect the cycles of nitrogen, sulfur
, and atmospheric oxidants.