REACTIONS OF AZINES WITH TITANOCENE - C-H ACTIVATION, C-C COUPLING, AND N-N CLEAVAGE TO HETEROBIMETALLIC COMPLEXES

Authors
OHFF A ZIPPEL T ARNDT P SPANNENBERG A KEMPE R ROSENTHAL U
Citation
A. Ohff et al., REACTIONS OF AZINES WITH TITANOCENE - C-H ACTIVATION, C-C COUPLING, AND N-N CLEAVAGE TO HETEROBIMETALLIC COMPLEXES, Organometallics, 17(9), 1998, pp. 1649-1651
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
9
Year of publication
1998
Pages
1649 - 1651
Database
ISI
SICI code
0276-7333(1998)17:9<1649:ROAWT->2.0.ZU;2-J
Abstract
Either C-H activation or C-C coupling is observed in reactions of tita nocene with azines ((RRC)-R-1-C-2=N-N=(CRR2)-R-1), which lead to the f ormation of complexes 2 and 3, respectively. The reaction with two dif ferent metallocene units can yield heterobimetallic bis(alkylideneamid o) complexes (4).