M. Fujita et al., THE LATTICE EVOLUTION OF THE SPIN-PEIERLS MATERIAL CUGEO3 STUDIED BY NEUTRON-SCATTERING, Physica. B, Condensed matter, 213, 1995, pp. 288-290
CuGeO3 is an inorganic compound which possesses a spin-Peierls transit
ion. We have studied the crystal structure and the phonon dynamics of
CuGeO3 by neutron scattering. We found that a lattice anomaly starts t
o evolve significantly above the transition temperature, T-sp, and the
re is a drastic change below T-sp. The phonon mode over a wide energy
range changes drastically at high temperature. Therefore we conclude t
hat the inherent structural instability in the crystal structure provi
des favorable conditions for the lattice-spin interaction and inducers
the spin-Peierls transition, i.e. lattice dimerization.