Citation
Rc. Maurya et R. Verma, SYNTHESIS AND CHARACTERIZATION OF SOME NOVEL MIXED-LIGAND CYANONITROSYL (MNNO)(6) COMPLEXES OF MANGANESE-(I) WITH BIOLOGICALLY-ACTIVE OXYGEN DONOR 2-PYRAZOLINE-5-ONE OR 3-PYRAZOLINE-5-ONE DERIVATIVES, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 37(2), 1998, pp. 147-150
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical
ISSN journal
03764710
→ ACNP
Volume
37
Issue
2
Year of publication
1998
Pages
147 - 150
Database
ISI
SICI code
0376-4710(1998)37:2<147:SACOSN>2.0.ZU;2-4
Abstract
A series of novel mixed-ligand cyanonitrosyl complexes on Mn(I) have b
een synthesized by the reaction of pentacyanonitrosylmanganate (I) ani
on ([Mn(NO)(CN)(5)](3-)) with 2- or 3-pyrazoline -5-one derivatives. T
he products which have been characterized by elemental analysis, molar
conductance measurements, magnetic susceptibility measurements, therm
ogravimetric analysis, electronic and IR spectral studies, have the ge
neral formula [Mn(NO)(CN)(2)(L)(2)(H2O)] (where L = 2- or 3-pyrazoline
-5-one derivatives). Octahedral configuration with low-spin {Mn(NO)}(
6) species has been suggested for these complexes.