SYNTHESIS AND CHARACTERIZATION OF [(RU(ETA(6)-C6ME6)CL-2)(2) (MU-DCBT)) AND ITS REACTION WITH EPH3 (E = P, AS, SB), 2,2'-BIPYRIDINE AND 1,10'-PHENANTHROLINE

Authors
PATHAK S GUPTA DK SAHAY AN PANDEY DS
Citation
S. Pathak et al., SYNTHESIS AND CHARACTERIZATION OF [(RU(ETA(6)-C6ME6)CL-2)(2) (MU-DCBT)) AND ITS REACTION WITH EPH3 (E = P, AS, SB), 2,2'-BIPYRIDINE AND 1,10'-PHENANTHROLINE, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 37(2), 1998, pp. 165-168
Citations number
26
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical
ISSN journal
03764710 → ACNP
Volume
37
Issue
2
Year of publication
1998
Pages
165 - 168
Database
ISI
SICI code
0376-4710(1998)37:2<165:SACO[(>2.0.ZU;2-Q
Abstract
Reaction of [{Ru(eta(6)-C6Me6)Cl-2}(2)] With 1,4-dicyano trans-2-buten e gives a binuclear complex [{Ru(eta(6)-C6Me6)Cl-2}(2) (mu-DCBT)] whic h undergoes metathetical reactions with EPh3 (E = P, As, Sb) and NN do nor bases, viz., 2,2'-bipyridine and I,10'-phenanthroline. The resulti ng products have been characterised by elemental analyses, IR. UV-Vis H-1 and C-13 NMR spectroscopy.