SYNTHESIS AND CHARACTERIZATION OF MANGANESE(III) COMPLEXES OF A CHIRAL DISULFONAMIDE LIGAND BASED ON TRANS-1,2-DIAMINOCYCLOHEXANE

Authors
BERNARDO K ROBERT A MEUNIER B
Citation
K. Bernardo et al., SYNTHESIS AND CHARACTERIZATION OF MANGANESE(III) COMPLEXES OF A CHIRAL DISULFONAMIDE LIGAND BASED ON TRANS-1,2-DIAMINOCYCLOHEXANE, Polyhedron, 16(14), 1997, pp. 2365-2368
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
14
Year of publication
1997
Pages
2365 - 2368
Database
ISI
SICI code
0277-5387(1997)16:14<2365:SACOMC>2.0.ZU;2-1
Abstract
The synthesis and characterization of an optically active disulfonamid e ligand based on trans-1,2-diaminocyclohexane as chiral motif is repo rted. The corresponding anionic manganese(III) complex has been evalua ted as potential catalyst for enantioselective olefin epoxidations, an d found to be inactive. (C) 1997 Elsevier Science Ltd.