SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC PROPERTIES OF [CU-I(ALKYLISOCYANIDE)(4)]BF4 COMPLEXES - X-RAY CRYSTAL-STRUCTURES OF [CU(MIBI)(4)]BF4 AND [CU(CPI)(4)]BF4

Authors
DEICAS B GAMBINO D KREMER C KREMER E MOMBRU A SUESCUN L MARIEZCURRENA R GONZALEZ O REY A MALLO L LEON A
Citation
B. Deicas et al., SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC PROPERTIES OF [CU-I(ALKYLISOCYANIDE)(4)]BF4 COMPLEXES - X-RAY CRYSTAL-STRUCTURES OF [CU(MIBI)(4)]BF4 AND [CU(CPI)(4)]BF4, Polyhedron, 16(14), 1997, pp. 2397-2403
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
14
Year of publication
1997
Pages
2397 - 2403
Database
ISI
SICI code
0277-5387(1997)16:14<2397:SCASPO>2.0.ZU;2-9
Abstract
Alkylisocyanide complexes of copper(I) with formula [Cu(CNR)(4)]BF4 [w here R = 2-methoxyisobutyl and 2-(carbomethoxy)-2-methylethyl] were sy nthesized by direct reaction of cuprous chloride with ligand. The stab ility of solid complexes and their aqueous solutions were tested by HP LC. Comparative studies were carried out on electronic, IR and H-1 NMR spectroscopy. Crystal structures of [Cu(MIBI)(4)]BF4 and [Cu(CPI)(4)] BF4 were determined from X-ray data and show a tetrahedral arrangement of ligands around the central copper atom in both compounds. (C) 1997 Elsevier Science Ltd.