ALLENYLMETHYLSILANE DERIVATIVE AS A SYNTHETIC EQUIVALENT OF 1,2,3-BUTATRIENE - SYNTHESIS AND REACTIONS OF DI-EXO-METHYLENECYCLOBUTANES AND DI-EXO-METHYLENECYCLOBUTENES

Authors
HOJO M MURAKAMI C NAKAMURA S HOSOMI A
Citation
M. Hojo et al., ALLENYLMETHYLSILANE DERIVATIVE AS A SYNTHETIC EQUIVALENT OF 1,2,3-BUTATRIENE - SYNTHESIS AND REACTIONS OF DI-EXO-METHYLENECYCLOBUTANES AND DI-EXO-METHYLENECYCLOBUTENES, Chemistry Letters, (4), 1998, pp. 331-332
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
4
Year of publication
1998
Pages
331 - 332
Database
ISI
SICI code
0366-7022(1998):4<331:ADAASE>2.0.ZU;2-P
Abstract
2-Methoxyallenylmethylsilane reacts with alkenes and alkynes in a [2 2] cycloaddition mode to give cyclobutanes and cyclobutenes, respecti vely. Cycloadducts are converted to di-exo-methylene compounds through 1,2-elimination of the methoxy and silyl groups. These di-exo-methyle necyclobutanes and -cyclobutenes react with alkenes and 1,3-dienes to afford fused bi- and tricyclic compounds.