PHASE-TRANSITIONS OF SCANDIUM TRIACETATE

Authors
OHTA Y MATSUO T SUGA H DAVID WIF IBBERSON RM
Citation
Y. Ohta et al., PHASE-TRANSITIONS OF SCANDIUM TRIACETATE, Physica. B, Condensed matter, 213, 1995, pp. 402-404
Citations number
4
Categorie Soggetti
Physics, Condensed Matter
Journal title
Physica. B, Condensed matter → ACNP
ISSN journal
09214526
Volume
213
Year of publication
1995
Pages
402 - 404
Database
ISI
SICI code
0921-4526(1995)213:<402:POST>2.0.ZU;2-C
Abstract
Lattice parameters of deuterated scandium triacetate have been determi ned by high-resolution neutron diffraction at temperatures between 5 a nd 200 K. Two phase transitions were located at 66 and 159 K in agreem ent with a calorimetric experiment. A large anisotropy of the thermal expansivity was found and it is discussed in terms of the different na ture of the chemical bonds combining the molecules in the crystal.