CATALYTIC EPOXIDATION OF ALPHA-PINENE OVER BIFUNCTIONAL MESOPOROUS MOLECULAR-SIEVES

Authors
ON DT KAPOOR MP JOSHI PN BONNEVIOT L KALIAGUINE S
Citation
Dt. On et al., CATALYTIC EPOXIDATION OF ALPHA-PINENE OVER BIFUNCTIONAL MESOPOROUS MOLECULAR-SIEVES, Catalysis letters, 44(3-4), 1997, pp. 171-176
Citations number
21
Categorie Soggetti
Chemistry Physical
Journal title
Catalysis letters → ACNP
ISSN journal
1011372X
Volume
44
Issue
3-4
Year of publication
1997
Pages
171 - 176
Database
ISI
SICI code
1011-372X(1997)44:3-4<171:CEOAOB>2.0.ZU;2-Z
Abstract
Bifunctional titanium-mesoporous molecular sieves containing different trivalent ions, e.g. B3+, Al3+ or Fe3+,were synthesized and character ized. These catalysts, which contain both acid and oxidizing catalytic sites, are very active in epoxidation of bulky olefins and highly sel ective in diol formation. A reasonably good stability and re-usability are also observed.