JOINT ROTATIONAL ANALYSIS OF 24 BANDS OF THE H2SE MOLECULE

Authors
ULENIKOV ON ONOPENKO GA",HAILIN,"ZHANG JH ZHOU ZY ZHU QS TOLCHENOV RN
Citation
On. Ulenikov et al., JOINT ROTATIONAL ANALYSIS OF 24 BANDS OF THE H2SE MOLECULE, Journal of molecular spectroscopy, 189(1), 1998, pp. 29-39
Citations number
15
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Journal title
Journal of molecular spectroscopy → ACNP
ISSN journal
00222852
Volume
189
Issue
1
Year of publication
1998
Pages
29 - 39
Database
ISI
SICI code
0022-2852(1998)189:1<29:JRAO2B>2.0.ZU;2-L
Abstract
A global fit of all currently available rotation-vibration energies ha s been made for 24 vibrational states of the (H2Se)-Se-80 molecule. Th e resulting set of 112 parameters reproduces the initial 3516 vibratio n-rotation energies with a mean accuracy of 10.6 x 10(-3) cm(-1). Usin g this model as a starting point, the rotational fine structure of the extremely weak local mode bands (13(+); 1)/(13(-); 1) and (06(+), 0)/ (06(-); 0) could be analyzed; the results are discussed. (C) 1998 Acad emic Press.