NEW ORGANIC METALS - BEDO-TTF BROMOMERCURATES

Authors
ZHILYAEVA EI LYUBOVSKAYA RN KONOVALIKHIN SV DYACHENKO ON LYUBOVSKII RB
Citation
Ei. Zhilyaeva et al., NEW ORGANIC METALS - BEDO-TTF BROMOMERCURATES, Synthetic metals, 94(1), 1998, pp. 35-40
Citations number
18
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
94
Issue
1
Year of publication
1998
Pages
35 - 40
Database
ISI
SICI code
0379-6779(1998)94:1<35:NOM-BB>2.0.ZU;2-M
Abstract
Electrochemical oxidation of BEDO-TTF (bis(ethylenedioxy)tetrathiafulv alene) in the: presence of Bu4NHgBr3 or Bu4NHgBr3 + Bu4NBr as a suppor ting electrolyte in 1,2-dichloroethane (DCE) allows the isolation of ( BEDO-TTF)(2)HgBr3, (BEDO-TTF)(5)Hg1.9Br6.8, (BEDO-TTF)(9)(HgBr4)(2) . 5DCE or (BEDO-TTF)Cl-0.5 . 1.5H(2)O radical cation salts depending on conditions of electrochemical synthesis. Conditions for the synthesis, crystal structures and conductivity of the resulting BEDO-TTF bromome rcurates are discussed. (C) 1998 Elsevier Science S.A. All rights rese rved.