CONVENIENT ACCESS TO PRIMARY AMINES BY EMPLOYING THE BARBIER-TYPE REACTION OF N-(TRIMETHYLSILYL)IMINES DERIVED FROM AROMATIC AND ALIPHATIC-ALDEHYDES

Authors
GYENES F BERGMANN KE WELCH JT
Citation
F. Gyenes et al., CONVENIENT ACCESS TO PRIMARY AMINES BY EMPLOYING THE BARBIER-TYPE REACTION OF N-(TRIMETHYLSILYL)IMINES DERIVED FROM AROMATIC AND ALIPHATIC-ALDEHYDES, Journal of organic chemistry, 63(9), 1998, pp. 2824-2828
Citations number
43
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
63
Issue
9
Year of publication
1998
Pages
2824 - 2828
Database
ISI
SICI code
0022-3263(1998)63:9<2824:CATPAB>2.0.ZU;2-P
Abstract
A new versatile preparation of primary amines via benzylation of aroma tic and aliphatic aldimines is described. Sonochemical and traditional methods for generation of the reactive intermediates are compared and contrasted. Competitive reactions were analyzed via free energy relat ionships to support the proposed alkylative mechanism.