Wr. Esposito et Ca. Floudas, GLOBAL OPTIMIZATION IN PARAMETER-ESTIMATION OF NONLINEAR ALGEBRAIC MODELS VIA THE ERROR-IN-VARIABLES APPROACH, Industrial & engineering chemistry research, 37(5), 1998, pp. 1841-1858
The estimation of parameters in nonlinear algebraic models through the
error-in-variables method has been widely studied from a computationa
l standpoint. The method involves the minimization of a weighted sum o
f squared errors subject to the model equations. Due to the nonlinear
nature of the models used, the resulting formulation is nonconvex and
may contain several local minima in the region of interest. Current me
thods tailored for this formulation, although computationally efficien
t, can only attain convergence to a local solution. In this paper, a g
lobal optimization approach based on a branch and bound framework and
convexification techniques for general twice differentiable nonlinear
optimization problems is proposed for the parameter estimation of nonl
inear algebraic models. The proposed convexification techniques exploi
t the mathematical properties of the formulation. Classical nonlinear
estimation problems were solved and will be used to illustrate the var
ious theoretical and computational aspects of the proposed approach.