Rm. Wajge et Gv. Reklaitis, AN OPTIMAL CAMPAIGN STRUCTURE FOR MULTICOMPONENT BATCH DISTILLATION WITH REVERSIBLE-REACTION, Industrial & engineering chemistry research, 37(5), 1998, pp. 1910-1916
When resource utilization and/or minimization of waste is comparable i
n importance to the production rate, the design of the operation polic
y should encompass an entire campaign of batches rather than a single
batch. This notion of campaign optimization is particularly relevant t
o batch distillation with reversible reaction which produces significa
nt amounts of off-cuts. Reprocessing these off-cuts merely based on co
nsideration of a single batch may lead not only to inefficient product
ion rates but also to the inefficient utilization of reactants. A gene
ral strategy for deciding the campaign structure for such an operation
is presented. The concept of distillation characteristic is introduce
d, and its exploitation is shown to result in a simple but effective r
eprocessing policy for off-cuts. The economic benefits of such a campa
ign structure are demonstrated with the help of a case study.