The scanning-laser-beam chemical imaging sensor was applied for the ob
servation of electrogenerated pH distribution on a mesoscopic scale. E
lectrolysis was carried out in potassium chloride solution and the res
ulting pH distribution was imaged with a 0.2 mm spatial resolution. As
a result, the generation of the pH distribution and its expansion to
the bulk region were clearly imaged. By examining the pH image, it was
also possible to obtain the pH values in the pH-distributed regions s
eparately from those in the bulk region.