SCANDIUM TRIFLATE-CATALYZED STRECKER-TYPE REACTIONS OF ALDEHYDES, AMINES AND TRIBUTYLTIN CYANIDE IN BOTH ORGANIC AND AQUEOUS-SOLUTIONS - ACHIEVEMENT OF COMPLETE RECOVERY OF THE TIN-COMPOUNDS TOWARD ENVIRONMENTALLY-FRIENDLY CHEMICAL PROCESSES

Authors
KOBAYASHI S BUSUJIMA T NAGAYAMA S
Citation
S. Kobayashi et al., SCANDIUM TRIFLATE-CATALYZED STRECKER-TYPE REACTIONS OF ALDEHYDES, AMINES AND TRIBUTYLTIN CYANIDE IN BOTH ORGANIC AND AQUEOUS-SOLUTIONS - ACHIEVEMENT OF COMPLETE RECOVERY OF THE TIN-COMPOUNDS TOWARD ENVIRONMENTALLY-FRIENDLY CHEMICAL PROCESSES, Chemical communications, (9), 1998, pp. 981-982
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
9
Year of publication
1998
Pages
981 - 982
Database
ISI
SICI code
1359-7345(1998):9<981:STSROA>2.0.ZU;2-7
Abstract
Scandium triflate (CF3SO3-)-catalyzed Strecker-type reactions were suc cessfully carried out by simply mixing aldehydes, amines and tributylt in cyanide at room temperature, to afford cr-amino nitriles in high yi elds. The reactions proceeded smoothly in both organic and aqueous sol utions, and complete recovery of the tin materials has been achieved.