SYSTEMATIC SYNTHESIS OF A SERIES OF HYDROPEROXO-PALLADIUM, ALKYLPEROXO-PALLADIUM AND MU-PEROXO-PALLADIUM COMPLEXES SUPPORTED BY THE HYDROTRIS(3,5-DIISOPROPYLPYRAZOLYL)BORATE LIGAND (TP(IPR)), TP(IPR)PD(PY)-OOX[X = PDTP(IPR)(PY), H, BU-T], VIA DEHYDRATIVE CONDENSATION OF A HYDROXO COMPLEX, TP(IPR)PD(PY)-OH

Authors
AKITA M MIYAJI T HIKICHI S MOROOKA Y
Citation
M. Akita et al., SYSTEMATIC SYNTHESIS OF A SERIES OF HYDROPEROXO-PALLADIUM, ALKYLPEROXO-PALLADIUM AND MU-PEROXO-PALLADIUM COMPLEXES SUPPORTED BY THE HYDROTRIS(3,5-DIISOPROPYLPYRAZOLYL)BORATE LIGAND (TP(IPR)), TP(IPR)PD(PY)-OOX[X = PDTP(IPR)(PY), H, BU-T], VIA DEHYDRATIVE CONDENSATION OF A HYDROXO COMPLEX, TP(IPR)PD(PY)-OH, Chemical communications, (9), 1998, pp. 1005-1006
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
9
Year of publication
1998
Pages
1005 - 1006
Database
ISI
SICI code
1359-7345(1998):9<1005:SSOASO>2.0.ZU;2-K
Abstract
A series of hydroperoxo, tert-butylperoxo and mu-peroxo complexes of p alladium, Tp(iPr)Pd(py)(OOX) [X = H, Bu-t, PdTp(iPr)(py); Tp(iPr): hyd rotris(3,5-diisopropylpyrazolyl)borate] is prepared by dehydrative con densation of a hydroxo complex, Tp(iPr)Pd(py)(OH), with HOOX.