ELUCIDATION OF THE MECHANISM OF ALKENE EPOXIDATION BY HYDROGEN-PEROXIDE CATALYZED BY TITANOSILICATES - A COMPUTATIONAL STUDY

Authors
TANTANAK D VINCENT MA HILLIER IH
Citation
D. Tantanak et al., ELUCIDATION OF THE MECHANISM OF ALKENE EPOXIDATION BY HYDROGEN-PEROXIDE CATALYZED BY TITANOSILICATES - A COMPUTATIONAL STUDY, Chemical communications, (9), 1998, pp. 1031-1032
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
9
Year of publication
1998
Pages
1031 - 1032
Database
ISI
SICI code
1359-7345(1998):9<1031:EOTMOA>2.0.ZU;2-9
Abstract
Calculated transition states for alkene epoxidation by hydrogen peroxi de, catalysed by titanosilicates, predict that it is the oxygen atom o f the titanium(IV)-hydroperoxide intermediate closer to the metal cent re which attacks the alkene.