BIHETEROCYCLIC LIGANDS, TRANSITION-METAL COMPLEXES OF 2-(1-PYRIDINE-2-THIONATO)BENZOXAZOLE AND 2-(1-PYRIDINE-2-THIONATO)BENZOTHIAZOLE SYNTHESIS AND CHARACTERIZATION

Authors
KHAN TA",SHAHJAHAN
Citation
Khan Ta",shahjahan, BIHETEROCYCLIC LIGANDS, TRANSITION-METAL COMPLEXES OF 2-(1-PYRIDINE-2-THIONATO)BENZOXAZOLE AND 2-(1-PYRIDINE-2-THIONATO)BENZOTHIAZOLE SYNTHESIS AND CHARACTERIZATION, Synthesis and reactivity in inorganic and metal-organic chemistry, 28(4), 1998, pp. 571-586
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
28
Issue
4
Year of publication
1998
Pages
571 - 586
Database
ISI
SICI code
0094-5714(1998)28:4<571:BLTCO2>2.0.ZU;2-#
Abstract
Several transition metal chelates with 2-(1-pyridine-2-thionato)benzox azole (PTBOX) and 2-(1-pyridine-2-thionato)benzothiazole (PTBTH) have been prepared and characterized. The ligands behave as a bidentate don ors coordinating through the nitrogen atom of the benzoxazole or benzo thiazole group and through the sulphur atom of the pyridine-2-thione m oiety. The ligand field spectra and the magnetic moment values suggest an octahedral geometry for the bivalent metal complexes. The Au(III) complex is proposed to have a trigonal bipyramidal stereochemistry. A chlorine-bridged dimeric structure has been suggested for the trivalen t metal complexes.