INFLUENCE OF CAPILLARITY ON CHEMICAL-STABILITY AND OF ELECTRIC-FIELD ON SURFACE-TENSION NEAR THE CRITICAL-POINT

Authors
Citation
A. Sanfeld, INFLUENCE OF CAPILLARITY ON CHEMICAL-STABILITY AND OF ELECTRIC-FIELD ON SURFACE-TENSION NEAR THE CRITICAL-POINT, Philosophical transactions-Royal Society of London. Physical sciences and engineering, 356(1739), 1998, pp. 819-828
Citations number
30
Categorie Soggetti
Multidisciplinary Sciences
ISSN journal
09628428
Volume
356
Issue
1739
Year of publication
1998
Pages
819 - 828
Database
ISI
SICI code
0962-8428(1998)356:1739<819:IOCOCA>2.0.ZU;2-W
Abstract
In the present paper, we show that the stability of a chemical reactio n occurring in a capillary layer depends on surface properties. A chem ical reaction unstable in a bulk phase may be stabilized in a surface layer and, vice versa, a stable reaction in a bulk phase may be unstab le when occurring at an interface. The second part of this paper shows how an applied electric field magi be responsible for a shift of the critical point through the effect on surface tension.