A. Sanfeld, INFLUENCE OF CAPILLARITY ON CHEMICAL-STABILITY AND OF ELECTRIC-FIELD ON SURFACE-TENSION NEAR THE CRITICAL-POINT, Philosophical transactions-Royal Society of London. Physical sciences and engineering, 356(1739), 1998, pp. 819-828
In the present paper, we show that the stability of a chemical reactio
n occurring in a capillary layer depends on surface properties. A chem
ical reaction unstable in a bulk phase may be stabilized in a surface
layer and, vice versa, a stable reaction in a bulk phase may be unstab
le when occurring at an interface. The second part of this paper shows
how an applied electric field magi be responsible for a shift of the
critical point through the effect on surface tension.