CHEMICAL SYNTHESIS OF 6-PYR)-GAL-BETA-1-]4GLCNAC-BETA-1-]3FUC-BETA-1-OME - A PYRUVATED TRISACCHARIDE RELATED TO THE CELL-AGGREGATION OF THESPONGE MICROCIONA-PROLIFERA
Sj. Deng et al., CHEMICAL SYNTHESIS OF 6-PYR)-GAL-BETA-1-]4GLCNAC-BETA-1-]3FUC-BETA-1-OME - A PYRUVATED TRISACCHARIDE RELATED TO THE CELL-AGGREGATION OF THESPONGE MICROCIONA-PROLIFERA, Journal of carbohydrate chemistry, 17(3), 1998, pp. 439-452
4,6-O-[(R)-1-carboxylethylidene] Gal beta 1-->4GlcNAc beta 1-->3Fuc be
ta 1-->OMe, a pyruvated trisaccharide unit involved in the aggregation
factor of the marine sponge Microciona prolifera, was synthesized ste
reospecifically and unambiguously employing thioglycosides as glycosyl
donors to construct glycosidic bonds.