Mb. Chang et Cf. Cheng, PLASMA-ASSISTED REMOVAL OF NO FROM GAS STREAMS VIA AMMONIA INJECTION, ENVIRONMENTAL ENGINEERING SCIENCE, 14(4), 1997, pp. 193-200
Removal of nitric oxide (NO) from gas streams via combined NH3 injecti
on with dielectric barrier discharge (DBD) plasmas was experimentally
investigated. Removal of NO was principally achieved via its reaction
with NHi radicals generated with DBD plasmas. Removal efficiency of NO
was measured as a function of stoichiometric ratio, applied voltage,
and inlet NO concentration of the gas stream. Experimental results sho
wed that as much as 80% of NO was removed from gas streams operating a
t room temperature. Increase in NH3/NO molar ratio and applied voltage
enhances NO removal efficiency. NO removal efficiency decreases sligh
tly as oxygen content in the gas stream increases from 0% to 6%, indic
ating the characteristic of selective reduction in this process. Howev
er, 15 ppmv N2O was detected with Fourier transform infrared for gas s
treams containing 6% by volume O-2 and 300 ppmv NO. Results of this st
udy indicated that conventional SNCR process could be operated at a mu
ch lower temperature by applying plasma technology to generate NHi rad
icals.