We investigate the electronic structure of twin boundaries in orthorho
mbically distorted high-T-c, materials using the quasiclassical theory
of superconductivity. At low temperatures we find a local instability
to a time-reversal symmetry breaking state at the twin boundary. This
state yields spontaneous currents along the twin boundary that are mi
croscopically explained by the structure of the quasiparticle bound st
ates. We calculate the local density of states and find a splitting in
the zero-bias peak once the spontaneous currents set in. This splitti
ng is measurable by STM techniques and is a unique signature of time-r
eversal breaking states at a twin boundary.