AN IMPROVED PROCEDURE FOR THE CONVERSION OF ALKENES AND GLYCALS TO 1,2-DIAZIDES USING MN(OAC)(3)CENTER-DOT-2H(2)O IN ACETONITRILE CONTAINING TRIFLUOROACETIC-ACID

Authors
SNIDER BB LIN H
Citation
Bb. Snider et H. Lin, AN IMPROVED PROCEDURE FOR THE CONVERSION OF ALKENES AND GLYCALS TO 1,2-DIAZIDES USING MN(OAC)(3)CENTER-DOT-2H(2)O IN ACETONITRILE CONTAINING TRIFLUOROACETIC-ACID, Synthetic communications, 28(10), 1998, pp. 1913-1922
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
10
Year of publication
1998
Pages
1913 - 1922
Database
ISI
SICI code
0039-7911(1998)28:10<1913:AIPFTC>2.0.ZU;2-2
Abstract
Alkenes and Glycals react with Mn(OAc3).2H(2)O and NaN3 in 9:1 acetoni trile-trifluoroacetic acid to give 1,2-diazides in >80% yield. Allylic azides are formed by slow addition of NaN3 to a mixture of alkene, Mn (OAc)(3).H2O and Cu(OAc)(2).