Cj. Kreher et al., VECTOR CORRELATIONS IN THE PHOTODISSOCIATION OF OCLO-(A)OVER-TILDE(2)A(2)(NU(1),0,0), Chemical physics letters, 286(5-6), 1998, pp. 389-397
Using resonant-enhanced multiphoton ionization combined with the time-
of-flight method, the photodissociation OClO((A) over tilde(2)A(2)) --
> ClO((XII)-I-2) + O(P-3) was investigated at two wavelengths which we
re found to give access to excitation below (397.5 nm) and above (359.
7 nm) the predicted exit barrier on the (A) over tilde(2)A(2) surface.
The complete angular correlations between the vectors mu, upsilon and
J for ClO(upsilon = 0) were determined at both wavelengths, providing
information on the direct and indirect dissociation pathways on the (
A) over tilde(2)A(2) surface of OClO. (C) 1998 Elsevier Science B.V.