OXIDATION OF 9-DECEN-1-OL (ROSALVA) BY AIR IN AQUEOUS-MEDIA ON PLATINUM CATALYSTS

Authors
CROZON AB BESSON M GALLEZOT P
Citation
Ab. Crozon et al., OXIDATION OF 9-DECEN-1-OL (ROSALVA) BY AIR IN AQUEOUS-MEDIA ON PLATINUM CATALYSTS, New journal of chemistry, 22(3), 1998, pp. 269-273
Citations number
36
Categorie Soggetti
Chemistry
Journal title
New journal of chemistry → ACNP
ISSN journal
11440546
Volume
22
Issue
3
Year of publication
1998
Pages
269 - 273
Database
ISI
SICI code
1144-0546(1998)22:3<269:OO9(BA>2.0.ZU;2-0
Abstract
Oxidation of 9-decen-1-ol to 9-decenoic acid was conducted in aqueous media (dioxane-water mixtures) in the presence of supported palladium or platinum catalysts. The beneficial effect on the activity of a bism uth promoter, deposited on the platinum particles by a redox reaction, was demonstrated. Operating in a mass-transport-limited regime improv es the resistance of the catalyst to deactivation by over-oxidation.