SCANNING-TUNNELING-MICROSCOPY STUDY OF THE SELF-ASSEMBLY OF 2-MERCAPTOPYRIMIDINE AND 4,6-DIMETHYL-2-MERCAPTOPYRIMIDINE ON AU(111)

Authors
DAVIS JJ HILL HAO YAMADA R NAOHARA H UOSAKI K
Citation
Jj. Davis et al., SCANNING-TUNNELING-MICROSCOPY STUDY OF THE SELF-ASSEMBLY OF 2-MERCAPTOPYRIMIDINE AND 4,6-DIMETHYL-2-MERCAPTOPYRIMIDINE ON AU(111), Journal of the Chemical Society. Faraday transactions, 94(9), 1998, pp. 1315-1319
Citations number
38
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Journal of the Chemical Society. Faraday transactions → ACNP
ISSN journal
09565000
Volume
94
Issue
9
Year of publication
1998
Pages
1315 - 1319
Database
ISI
SICI code
0956-5000(1998)94:9<1315:SSOTSO>2.0.ZU;2-3
Abstract
Well ordered molecular domains of 2-mercaptopyrimidine and 4,6-dimethy l-2-mercaptopyrimidine on gold have been imaged. In contrast to alkyl thiol films, where the arrangement is largely, if not exclusively, det ermined by the underlying gold lattice, intermolecular interactions be tween these molecules appear to be important. A striking 'side-on' arr angement of 2-mercaptopyrimidine molecules has been observed.