SEQUENTIAL EPOXIDE FRAGMENTATION RADICAL CYCLIZATIONS MEDIATED BY SAMARIUM(II) IODIDE

Authors
MOLANDER GA LOSADA CD
Citation
Ga. Molander et Cd. Losada, SEQUENTIAL EPOXIDE FRAGMENTATION RADICAL CYCLIZATIONS MEDIATED BY SAMARIUM(II) IODIDE, Tetrahedron, 54(22), 1998, pp. 5819-5832
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
22
Year of publication
1998
Pages
5819 - 5832
Database
ISI
SICI code
0040-4020(1998)54:22<5819:SEFRCM>2.0.ZU;2-7
Abstract
A sequential reductive coupling process promoted by samarium(II) iodid e is described. Cascade epoxide ring opening and two sequential radica l cyclizations lead to a variety of bicyclo[m.n.0] systems as mixtures of diastereomers. (C) 1998 Elsevier Science Ltd. All rights reserved.