ACETYLATION AND FORMYLATION OF ALCOHOLS WITH TRIPHENYLPHOSPHINE AND CARBON TETRABROMIDE IN ETHYL-ACETATE OR ETHYL FORMATE

Authors
HAGIWARA H MOROHASHI K SAKAI H SUZUKI T ANDO M
Citation
H. Hagiwara et al., ACETYLATION AND FORMYLATION OF ALCOHOLS WITH TRIPHENYLPHOSPHINE AND CARBON TETRABROMIDE IN ETHYL-ACETATE OR ETHYL FORMATE, Tetrahedron, 54(22), 1998, pp. 5845-5852
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
22
Year of publication
1998
Pages
5845 - 5852
Database
ISI
SICI code
0040-4020(1998)54:22<5845:AAFOAW>2.0.ZU;2-D
Abstract
Alcohols were acetylated or formylated with triphenylphosphine and car bon tetrabromide in ethyl acetate or ethyl (or methyl) formate at room temperature. THP or TBDMS ether of primary alcohol got converted into formate or acetate under the experimental conditions employed in one pot operation. (C) 1998 Elsevier Science Ltd. All rights reserved.