SOLVENT-FREE AZIRIDINATION OF ALPHA-NITROALKENES

Authors
FIORAVANTI S PELLACANI L STABILE S TARDELLA PA BALLINI R
Citation
S. Fioravanti et al., SOLVENT-FREE AZIRIDINATION OF ALPHA-NITROALKENES, Tetrahedron, 54(22), 1998, pp. 6169-6176
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
22
Year of publication
1998
Pages
6169 - 6176
Database
ISI
SICI code
0040-4020(1998)54:22<6169:SAOA>2.0.ZU;2-H
Abstract
NsONHCO(2)Et in the presence of CaO reacts without solvent with alpha- nitroalkenes to give 1-(ethoxycarbonyl)-2-nitroaziridines (62-84%). a possible involvement of an aza-Michael route is proposed on the basis of regio- and stereochemical reaction outcome, compared also with the results of thermolysis of ethyl azidoformate on the same alpha-nitroal kenes. (C) 1998 Elsevier Science Ltd. All rights reserved.