EFFICIENT CONVERSION OF NO INTO N2O BY SELECTED ELECTROREDUCED HETEROPOLYANIONS

Citation
A. Belhouari et al., EFFICIENT CONVERSION OF NO INTO N2O BY SELECTED ELECTROREDUCED HETEROPOLYANIONS, New journal of chemistry, 22(2), 1998, pp. 83-86
Citations number
17
Categorie Soggetti
Chemistry
Journal title
ISSN journal
11440546
Volume
22
Issue
2
Year of publication
1998
Pages
83 - 86
Database
ISI
SICI code
1144-0546(1998)22:2<83:ECONIN>2.0.ZU;2-L
Abstract
It is shown that a series of one- and two-electron-reduced heteropolya nions of the Keggin- and Dawson-types convert quantitatively NO into N 2O in acidic aqueous media. The corresponding oxidized forms of the he teropolyanions are fully regenerated. Unsubstituted and lacunary heter opolyanions, as well as the substituted heteropolyanions of these two groups, prove active in this context.