ALKYLIDENE-DITHIOCARBAMATE COUPLING - CRYSTAL-STRUCTURE OF 4OME-(4))SC(NC4H8)S)(KAPPA(2)-S2CNC4H8)(CO)(PPH3)]

Authors
COOK DJ HARLOW KJ HILL AF WELTON T WHITE AJP WILLIAMS DJ
Citation
Dj. Cook et al., ALKYLIDENE-DITHIOCARBAMATE COUPLING - CRYSTAL-STRUCTURE OF 4OME-(4))SC(NC4H8)S)(KAPPA(2)-S2CNC4H8)(CO)(PPH3)], New journal of chemistry, 22(4), 1998, pp. 311-313
Citations number
17
Categorie Soggetti
Chemistry
Journal title
New journal of chemistry → ACNP
ISSN journal
11440546
Volume
22
Issue
4
Year of publication
1998
Pages
311 - 313
Database
ISI
SICI code
1144-0546(1998)22:4<311:AC-CO4>2.0.ZU;2-A
Abstract
The reaction of [Ru(=CC6H4OMe-4)Cl(CO)(PPh3)(2)] with [NH4][S2CNC4H8] provides the structurally characterised metallacycle (2)-CH(C6H4OMe-4) SC(NC4H8)S}(S2CNC4H8)(CO)(PPh3)], related examples of which arise from the reactions of xanthate or dithiocarbamate salts with the alkyliden e compounds [MCl2(=CHR)(CO)(PPh3)(2)](M = Ru or Os; R = Ph or C6H4OMe- 4) and [OsCl(=CHR)(OH2)(CO)(PPh3)(2)]ClO4.