Cw. Mccurdy et al., CALCULATION OF SCATTERING-AMPLITUDES AS CONTINUOUS-FUNCTIONS OF ENERGY - R-MATRIX THEORY WITHOUT A BOX, Physical review. A, 57(5), 1998, pp. 3511-3517
An extension of the Kohn variational method for computing scattering a
mplitudes is demonstrated that requires only matrix elements of the re
solvent of the Hamiltonian between energy-independent test functions.
Scattering boundary conditions are imposed by expanding the resolvent
in a basis of square-integrable functions and outgoing-wave continuum
functions. By employing several continuum basis functions with overlap
s defined by suitable analytic continuation, the scattering amplitude
can be expressed efficiently over a continuous range of energies. The
method described here differs from previous approaches using time-inde
pendent wave packets in that the wave packets which generate the initi
al and final states in this approach can lie within the interaction re
gion.