SYNTHESIS AND PHYSICAL-PROPERTIES OF NEW METALLIC COMPOUND LIXC60(THF)(Y)

Authors
MORIYAMA H ABE M MOTOKI H WATANABE T HAYASHI S KOBAYASHI H
Citation
H. Moriyama et al., SYNTHESIS AND PHYSICAL-PROPERTIES OF NEW METALLIC COMPOUND LIXC60(THF)(Y), Synthetic metals, 94(2), 1998, pp. 167-171
Citations number
25
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
94
Issue
2
Year of publication
1998
Pages
167 - 171
Database
ISI
SICI code
0379-6779(1998)94:2<167:SAPONM>2.0.ZU;2-A
Abstract
Electrocrystallization of C-60 in chlorobenzene and lithium tetrapheny lborate in THF efficiently produced the new metallic species LixC60(TH F)(y); the ESR spectra show clearly the existence of a typical broad s ignal due to the C-60 anion radical. The change of the intensity of th e ESR signal corresponds to the metal-insulator transition at 150 K, a nd the C-13 and Li-7 solid-state NMR spectra are also reported. (C) 19 98 Elsevier Science S.A. All rights reserved.