PHOTOINDUCED ABSORPTION-SPECTRA OF POLY[1,6-DI(N-CARBAZOLYL)-2,4-HEXADIYNE] (POLYDCHD) BY EXCITATION ON THE CARBAZOLE GROUP

Citation
D. Comoretto et al., PHOTOINDUCED ABSORPTION-SPECTRA OF POLY[1,6-DI(N-CARBAZOLYL)-2,4-HEXADIYNE] (POLYDCHD) BY EXCITATION ON THE CARBAZOLE GROUP, Synthetic metals, 94(2), 1998, pp. 229-234
Citations number
28
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
ISSN journal
03796779
Volume
94
Issue
2
Year of publication
1998
Pages
229 - 234
Database
ISI
SICI code
0379-6779(1998)94:2<229:PAOP>2.0.ZU;2-Z
Abstract
We report photoinduced absorption measurements in the millisecond time domain of poly[ 1,6-di(N-carbazolyl)-2,4-hexadiyne] (poly-DCHD) obtai ned by pumping on the side group. We show that the photoexcited states are similar to those detected by pumping on the absorption band of th e conjugated backbone. This fact can be explained in terms of fast mig ration of the excitation energy from the side group to the conjugated chain. (C) 1998 Elsevier Science S.A. All rights reserved.