TERMS OF A HYDROGEN MOLECULE IN A HIGH MAGNETIC-FIELD

Citation
Ma. Liberman et Av. Petrov, TERMS OF A HYDROGEN MOLECULE IN A HIGH MAGNETIC-FIELD, Physica scripta. T, 57(5), 1998, pp. 573-580
Citations number
30
Categorie Soggetti
Physics
Journal title
ISSN journal
02811847
Volume
57
Issue
5
Year of publication
1998
Pages
573 - 580
Database
ISI
SICI code
0281-1847(1998)57:5<573:TOAHMI>2.0.ZU;2-X
Abstract
Analytical expressions for the pair interaction potential between hydr ogen atoms in a high magnetic held are derived for the triplet and sin glet terms. The results are asymptotically exact for large interatomic distance R compared with the atomic size and in the limit of ultrahig h magnetic fields. It is shown that the ground state of the hydrogen m olecule in a high magnetic field is the triplet term (3) Pi(u), which corresponds to the case when one atom is in the ground state and the o ther is in the first excited state. The interaction between two ground -state hydrogen atoms in the term (3) Sigma(u) is very weak. The energ y of the singlet term (1) Sigma(g) has a deep minimum, which is much h igher than the triplet one and may be a metastable state of a hydrogen molecule only.