TERM ANALYSIS AND HYPERFINE-STRUCTURE IN NEUTRAL VANADIUM

Citation
P. Palmeri et al., TERM ANALYSIS AND HYPERFINE-STRUCTURE IN NEUTRAL VANADIUM, Physica scripta. T, 55(5), 1997, pp. 586-598
Citations number
54
Categorie Soggetti
Physics
Journal title
ISSN journal
02811847
Volume
55
Issue
5
Year of publication
1997
Pages
586 - 598
Database
ISI
SICI code
0281-1847(1997)55:5<586:TAAHIN>2.0.ZU;2-Q
Abstract
High resolution spectra of neutral vanadium excited in a hollow cathod e discharge with helium, neon and argon as carrier gases have been rec orded in the infrared region (1800-9000cm(-1)) by Fourier transform sp ectroscopy. A detailed analysis of the spectra has allowed to determin e some missing terms in the doublet, quartet and sextet systems of the configurations 3d(5), 3d(3)4s5p, 3d(4)4s, 3d(4)5p and 3d(4)5d of VI. Investigation of the hyperfine structure patterns has confirmed the id entification of the transitions and has given rise to the determinatio n of 67 new magnetic dipole constants.