SPECTROSCOPIC INVESTIGATIONS ON VANADYL DOPED CADMIUM STRUVITE

Authors
RAVIKUMAR RVSSN MADHU N REDDY BJ REDDY YP RAO PS
Citation
Rvssn. Ravikumar et al., SPECTROSCOPIC INVESTIGATIONS ON VANADYL DOPED CADMIUM STRUVITE, Physica scripta. T, 55(5), 1997, pp. 637-638
Citations number
11
Categorie Soggetti
Physics
Journal title
Physica scripta. T → ACNP
ISSN journal
02811847
Volume
55
Issue
5
Year of publication
1997
Pages
637 - 638
Database
ISI
SICI code
0281-1847(1997)55:5<637:SIOVDC>2.0.ZU;2-Z
Abstract
EPR and optical spectra of vanadyl doped Cadmium Ammonium Phosphate He xa Hydrate (CAPH) are investigated both at room and liquid nitrogen te mperatures. The results and analysis reveal that the site symmetry of the VO2+ ion is tetragonal (C-4v). The following crystal field and spi n Hamiltonian parameters are evaluated. Dq = 1600 cm(-1), Ds = - 3275 cm(-1) and Dt = 488 cm(-1), g parallel to = 1.931, g perpendicular to = 1.993, A parallel to = 183 x 10(-4) cm(-1), A perpendicular to = 72 x 10(-4) cm(-1).