TRANSITION-METAL-CATALYZED DIBORATION

Authors
MARDER TB NORMAN NC
Citation
Tb. Marder et Nc. Norman, TRANSITION-METAL-CATALYZED DIBORATION, Topics in catalysis, 5(1-4), 1998, pp. 63-73
Citations number
69
Categorie Soggetti
Chemistry Physical","Chemistry Applied
Journal title
Topics in catalysis → ACNP
ISSN journal
10225528
Volume
5
Issue
1-4
Year of publication
1998
Pages
63 - 73
Database
ISI
SICI code
1022-5528(1998)5:1-4<63:TD>2.0.ZU;2-O
Abstract
Homogeneous transition metal catalysed hydroboration reactions are dis cussed briefly, providing the background which led to the recent disco very of metal catalysed diborations [additions of the B-B bond in B-2( OR)(4) compounds] of alkynes, alkenes, 1,3-diynes, 1,3-dienes, and alp ha,beta-unsaturated ketones. Catalysed additions of B-Si and B-Sn bond s are also presented. Metal catalysed synthesis of organoboron compoun ds is a useful new synthetic method.