SOLVENT EFFECTS FOR PROTON-TRANSFER REACTION FROM DIMETHYL(4-NITROPHENYL)MALONATE TO CIS 1,2-BIS(DIETHYLAMINOMETHYL)CYCLOHEXANE

Authors
SCHROEDER G LESKA B BRZEZINSKI B
Citation
G. Schroeder et al., SOLVENT EFFECTS FOR PROTON-TRANSFER REACTION FROM DIMETHYL(4-NITROPHENYL)MALONATE TO CIS 1,2-BIS(DIETHYLAMINOMETHYL)CYCLOHEXANE, Journal of molecular structure, 446(3), 1998, pp. 235-239
Citations number
10
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
446
Issue
3
Year of publication
1998
Pages
235 - 239
Database
ISI
SICI code
0022-2860(1998)446:3<235:SEFPRF>2.0.ZU;2-3
Abstract
The influence of polar aprotic solvents: DMSO, AN and HMPA on the kine tics of proton transfer reactions from dimethyl(4-nitrophenyl)malonate (C-acid) to cis 1,2-bis-(diethylaminomethyl)cyclohexane (DEAMCH) was studied. On the basis of the kinetic parameters obtained, the multiste p mechanism of deprotonation processes and the influence of solvation on transition state were discussed. (C) 1998 Elsevier Science B.V.