Deep-level defects appear in silicon upon heat treatment of wafers wit
h surface disordered by mechanical lapping or introducing high concent
ration impurity in diffusion layer, i.e. in regimes typical of fabrica
tion of high voltage devices. By means of capacitance transient spectr
oscopy, combined with other methods, it was shown that dominant electr
on traps with ionization energies of 0.28 and 0.54 eV of double level
donor have low recombination activity, but affect the resistivity of h
igh purity Si and play a key role in limiting the p-n junction breakdo
wn voltage V-b. A careful study of the defect parameters showed their
similarity to sulphur-related centres in Si.